Alkene Polymerization Reactions with Transition Metal Catalysts

  • Author : Yury Kissin
  • Publsiher : Elsevier
  • Release : 10 March 2008
  • ISBN : 0080557996
  • Page : 495 pages
  • Rating : 4/5 from 21 voters

Download or read online book entitled Alkene Polymerization Reactions with Transition Metal Catalysts written by Yury Kissin and published by Elsevier. This book was released on 10 March 2008 with total page 495 pages. Available in PDF, EPUB and Kindle. Get best books that you want by click Get Book Button and Read as many books as you like. Book Excerpt : During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
Author: Yury Kissin
Publisher: Elsevier
Relase: 2008-03-10
ISBN: 0080557996
GET BOOK

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
Author: Y. V. Kissin
Publisher: Elsevier Science & Technology
Relase: 2008
ISBN: 1435628756
GET BOOK

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts
Author: Ray Hoff
Publisher: John Wiley & Sons
Relase: 2018-04-20
ISBN: 9781119242154
GET BOOK

Introduction to Industrial Polypropylene

Introduction to Industrial Polypropylene
Author: Dennis B. Malpass,Elliot Band
Publisher: John Wiley & Sons
Relase: 2012-07-02
ISBN: 9781118463208
GET BOOK

Transition Metals and Organometallics as Catalysts for Olefin Polymerization

Transition Metals and Organometallics as Catalysts for Olefin Polymerization
Author: Walter Kaminsky
Publisher: Springer Verlag
Relase: 1988
ISBN: UOM:39015016099015
GET BOOK

Handbook of Industrial Polyethylene and Technology

Handbook of Industrial Polyethylene and Technology
Author: Mark A. Spalding,Ananda Chatterjee
Publisher: John Wiley & Sons
Relase: 2017-10-26
ISBN: 9781119159773
GET BOOK

Transition Metal Catalyzed Polymerizations

Transition Metal Catalyzed Polymerizations
Author: Roderic P. Quirk
Publisher: Taylor & Francis
Relase: 1983
ISBN: 3718601435
GET BOOK

Homogeneous Transition metal Catalysis

Homogeneous Transition metal Catalysis
Author: Christopher Masters
Publisher: Springer Science & Business Media
Relase: 2012-12-06
ISBN: 9789400958807
GET BOOK

Inorganic Reactions and Methods The Formation of Bonds to Transition and Inner Transition Metals

Inorganic Reactions and Methods  The Formation of Bonds to Transition and Inner Transition Metals
Author: A. P. Hagen
Publisher: John Wiley & Sons
Relase: 2009-09-17
ISBN: 9780470145500
GET BOOK

Carraher s Polymer Chemistry Tenth Edition

Carraher s Polymer Chemistry  Tenth Edition
Author: Charles E. Carraher Jr.
Publisher: CRC Press
Relase: 2017-10-12
ISBN: 9781498737494
GET BOOK

Introduction to Polymer Chemistry

Introduction to Polymer Chemistry
Author: Charles E. Carraher Jr.
Publisher: CRC Press
Relase: 2017-01-06
ISBN: 9781498737852
GET BOOK

Introduction to Polymer Chemistry Third Edition

Introduction to Polymer Chemistry  Third Edition
Author: Charles E. Carraher Jr.
Publisher: CRC Press
Relase: 2012-12-04
ISBN: 9781466554948
GET BOOK

Carraher s Polymer Chemistry Ninth Edition

Carraher s Polymer Chemistry  Ninth Edition
Author: Charles E. Carraher Jr.
Publisher: CRC Press
Relase: 2016-04-19
ISBN: 9781466552203
GET BOOK

Carraher s Polymer Chemistry Eighth Edition

Carraher s Polymer Chemistry  Eighth Edition
Author: Charles E. Carraher Jr.
Publisher: CRC Press
Relase: 2010-10-13
ISBN: 9781439809563
GET BOOK