Alkene Polymerization Reactions with Transition Metal Catalysts

  • Author : Yury Kissin
  • Publsiher : Elsevier
  • Release : 10 March 2008
  • ISBN : 0080557996
  • Page : 495 pages
  • Rating : 4/5 from 21 voters

Download or read online book entitled Alkene Polymerization Reactions with Transition Metal Catalysts written by Yury Kissin and published by Elsevier. This book was released on 10 March 2008 with total page 495 pages. Available in PDF, EPUB and Kindle. Get best books that you want by click Get Book Button and Read as many books as you like. Book Excerpt : During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts
Author: Yury Kissin
Publisher: Elsevier
Relase: 2008-03-10
ISBN: 0080557996
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Handbook of Transition Metal Polymerization Catalysts
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Proceedings of the National Academy of Sciences of the United States of America

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Solution Structures of Two Homogeneous Early Transition metal Olefin Polymerization Catalysts

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Step growth Polymers for High performance Materials

Step growth Polymers for High performance Materials
Author: James L. Hedrick,American Chemical Society,Jeff W. Labadie,American Chemical Society. Division of Polymer Chemistry,American Chemical Society. Meeting,Calif.) American Chemical Society Meeting 1995 (Anaheim
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